![]() ^ France, Colin (2008), The Reactivity Series of Metals.Reactivity (chemistry), which discusses the inconsistent way that the term 'reactivity' is used in chemistry.This is borne out by the extraction of metallic lithium by the electrolysis of a eutectic mixture of lithium chloride and potassium chloride: lithium metal is formed at the cathode, not potassium. The same as the reverse order of the (gas-phase) ionization energies. Potassium > sodium > lithium > alkaline earth metals, The order of reactivity, as shown by the vigour of the reaction with water or the speed at which the metal surface tarnishes in air, appears to be Even with this proviso, the electrode potentials of lithium and sodium and gold – and hence their positions in the electrochemical series – appear anomalous. However, they are only valid for standard conditions: in particular, they only apply to reactions in aqueous solution. Standard electrode potentials offer a quantitative measure of the power of a reducing agent, rather than the qualitative considerations of other reactive series. The positions of lithium and sodium are changed on such a series. Greyed-out rows indicate values based on estimation rather than experiment. Some other elements in the middle of the 4d and 5d rows have been omitted (Zr–Tc, Hf–Os) when their simple cations are too highly charged or of rather doubtful existence. ![]() Metallicity has been defined by the " stairstep line", so germanium and antimony have been included, but not astatine (whose simple cation is doubtful in any case). Hydrogen has been included as a benchmark, although it is not a metal. (In any case, the typical oxidation states for the most accessible seventh-period elements thorium and uranium are too high to allow a direct comparison.) In the first six periods this does not make a difference to the relative order, but in the seventh period it does, so the seventh-period elements have been excluded. ![]() However, not all sources give the same values: there are some differences between the precise values given by NIST and the CRC Handbook of Chemistry and Physics. It is mostly based on tables provided by NIST. The following list includes the metallic elements of the first six periods. The reactivity series is sometimes quoted in the strict reverse order of standard electrode potentials, when it is also known as the " electrochemical series". Copper and silver will react with nitric acid but because nitric acid is an oxidizing acid, the oxidizing agent is not the H + ion as in normal acids, but the NO 3 − ion.Ĭomparison with standard electrode potentials Magnesium, aluminium and zinc can react with water, but the reaction is usually very slow unless the metal samples are specially prepared to remove the surface layer of oxide which protects the rest of the metal. There is some ambiguity at the borderlines between the groups. Metals in the middle of the reactivity series, such as iron, will react with acids such as sulfuric acid (but not water at normal temperatures) to give hydrogen and a metal salt, such as iron(II) sulfate:įe (s) + H 2SO 4 (l) → FeSO 4 (aq) + H 2 (g) The most reactive metals, such as sodium, will react with cold water to produce hydrogen and the metal hydroxide:Ģ Na (s) + 2 H 2O (l) →2 NaOH (aq) + H 2 (g) There is no unique and fully consistent way to define the reactivity series, but it is common to use the three types of reaction listed below, many of which can be performed in a high-school laboratory (at least as demonstrations). become stronger reducing agents ( electron donors).require more energy (and different methods) to be isolated from their compounds.lose electrons ( oxidize) more readily to form positive ions.Going from the bottom to the top of the table the metals: May react with some strong oxidizing acids Reacts with acids very poor reaction with steam Or less commonly other alkali metals, hydrogen or calcium in the Kroll process Pyrometallurgical extraction using magnesium, In boiling water, and very vigorously with acids Reacts very slowly with cold water, but rapidly ![]() It is used to summarize information about the reactions of metals with acids and water, single displacement reactions and the extraction of metals from their ores. In chemistry, a reactivity series (or activity series) is an empirical, calculated, and structurally analytical progression of a series of metals, arranged by their "reactivity" from highest to lowest. Not to be confused with Electrochemical series.
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![]() ![]() ![]() First, we must copy tweet link where the video we want to download is located.If you are already a user of this fantastic application, then I will show you the steps to follow to download Twitter videos: With this application, we can also extract audio from videos, convert audio files to other formats, access cloud storage platforms. One of the best apps available on iOS for download videos from any platform It's Amerigo. We can remove the ads by paying an annual subscription or by purchasing the app for life. Twitterrific is available for your download for free and includes ads. The video will be downloaded automatically and will be stored in the Photos app of our device. Finally, we move to the option save video.Once playback has started, press and hold the video until the iOS share menu appears.Next, we click on the video so that start playback.First of all, we headed to the tweet where the video is located.To download a Twitter video on iPhone or iPad with Twitterrific, we must perform the steps that I show you below: This application, allows us to download videos from Twitter directly without having to resort to third-party applications, keyboard shortcuts, web pages. Twitterrrific is one of these applications. In addition to the official Twitter app for iOS, in the App Store too we can find third-party applications that also allow us to access Twitter, thus getting rid of the large number of ads that the platform displays. This shortcut works both through the official Twitter app and on Twitter. If we have previously used a shortcut that has asked us for permission to access the Photos application, this new shortcut, will not request it again. Next, it will ask us again for permission to connect to the website with which the video will be downloaded.The higher the quality, the more space it will occupy on our device. Next, the application will invite us to select video quality.Click on Always allow to prevent you from asking us again in the future. The first time we run it, will ask us for permission to connect to.Next, click on the share button and select the TVDL shortcut.The first thing we must do is go to the tweet where the video we want to download is located.To withdraw from your download twitter videos with this shortcut, we must follow the steps that I show you below: In addition, it is open source, so any user you can check its operation. The best thing about this shortcut (there are others available) is that it allows us to select video quality, in order to reduce the file size or maintain the highest possible video quality. With the TVDL (Twitter Video Downloader) shortcut, available at this link we can download any video from twitter. ![]() Squad AI is a set list of sequenced priorities that does not change. though I haven't actually checked if the summoner update changed that. That's why the only good squad job for aoes is arcanist, for shadow flare and emerald carbuncle. Squads use their aoe abilities randomly (or rather, as part of a set sequence), regardless of the number of enemies. We've got 8 members in our squadron, so let us send out two special missions at once. Also update squadrons to use the trust ai system, instead of the squadron command system. Let us view all squadron recruits from a list, instead of one at a time in the order of arrival.įor trusts, let us choose between trust avatars or squadron members. Grand companies are a way for the nations to mobilize adventurers for specific goals where their own manpower or resources may be inadequate or occupied.Īllow you to undertake special challenges with squadrons to earn job crystals for them, and expand their options to include all existing jobs. A few quests from each would answer any questions about the decision to model a new organization to integrate adventurers into the command structures for each nation after the successful examples from the Eorzean city states. Regarding a comment that this is not lore friendly, it absolutely can be. For the purposes of pvp content have them allied with Gridania, Ul'Dah, and Limsa respectively. Merge all seals into a single Grand Company Seals, instead of each being separateĪdd grand companies for Ishgard, Ala Mhigo, and Doma. I want to see the following happen with them: Grand companies in general feel like forgotten content. I made a comment like a week ago about Grand Companies and what I want to see. This will display as: Hildibrand is my hero.If you're posting a submission with spoilers in the body or potentially comments, click "spoiler" after you've submitted it.If you're unsure if something is a spoiler, spoiler tag it just to be safe.Fanworks must be credited to the author, not be rehosted without permission, not advertise artists for profit.Avoid these restricted types of posts: Repetitive / Definitive FAQ.Parts of the FFXIV User Agreement are enforced.Be civil and respectful, no name shaming.Subreddit Legend: Posting Rules: ( full list) FINAL FANTASY XIV Materials Usage License Revised.Actions Taken Against In-Game RMT & Other Illicit Activities (Jun.Actions Taken Against In-Game RMT & Other Illicit Activities (Jul.FINAL FANTASY XIV: ENDWALKER – EP4 Available Now!.Pre-orders Open for Encyclopædia Eorzea Volume III. ![]() New Optional Items & Limited-time Sale!.Online Store / Mog Station Maintenance (Jun.Server Status: Online Current Countdown Arrived Patch 6.41 Current Patch ( more) Current Patch: 6.4 Live Letter Part LXXVII Summary Subreddit Monthly Meta: June ![]() It's possible that Levinson chose to break the show's continuity and adjust Fez's age so he could better fit in with the other characters and storylines on "Euphoria. Rue's comment seems to imply that Fez's age has been altered to fit his season two storyline and blossoming romance with Lexi.Ĭloud told GQ that his character was originally supposed to get killed off on season one, but showrunner Sam Levinson decided to keep Fez around. ![]() "She couldn't remember the last time someone her age asked her so many questions about herself," Rue says of Lexi and Fez's conversation. Hunter Schafer as Jules on season two, episode three of 'Euphoria. Hunter Schafer portrays a 17-year-old junior named Jules Vaughn. ![]() On season one, episode seven, Nate said that Fez "dropped out of school at 20." But on season two, episode two, Rue, in the narration, alludes to his age while talking about his New Year's Eve interaction with Lexi. In September 2020, Zendaya became the youngest star to win an Emmy for best actress in a drama series, for her performance on season one of 'Euphoria.' She was 24 years old at the time. The season two premiere gives viewers a look at Fez's backstory and explains how he became a drug dealer. While McKay and Cassie were making out in his room, a very disturbing scene happened. He's first introduced as Rue's drug-dealing friend. Whatever Actually Happened, McKay Was Certainly Assaulted. It often indicates a user profile.Īngus Cloud as Fezco on season two, episode four of "Euphoria." Account icon An icon in the shape of a person's head and shoulders. ![]()
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I looked for support on the Web and found that Mac OS support was on the linuxham forum. Certainly the audio was getting to FLDIGI, as PSK31 worked fine, but when you switched to another digital mode, nothing I used ARRL Bulletin transmissions to test FLDIGI on those modes.įLDIGI does decode psk31 quite well with no problems, so I assumed that the problem was internal to FLDIGI. FLDIGI wouldn't decode RTTY and MFSK, and possibly other modes, but it would decode PSK31. But lately I upgraded my Mac OS to Big Sur and ran into problems. I've used FLDIGI for many years, and it's always worked great. It is, hands down, the BEST decoding engine I have used.and I have used them all(if set to the highest level in menu.better have a fast puter tho.lol) Keep in mind, this is FREE software that is cross-platform.the world is not perfect. Like some, I have also had "issues"(crashes). I have been running FLDigi for many, many years andĪFSK vs FSK(RTTY).With the soundcard/interfaceĪdjusted right, you CAN NOT tell the diff. And I for one am GLAD it does not support FT8,etc!!!Īnd hope it never does. It does RTTY just as well or better than my KAM or old UTU. And Dave and the groups support is first class. It is by far the BEST digi-mode software out there(Free or paid)ĭave has really put in the work and kept it up to date. Not tied into any one thing with this software.īeen running FLDigi A LONG TIME! Almost since it began. ![]() Very Nice to pick the mode to operate under pending propagation etc. I always look forward to new releases to see what the development team have included as new things arrive in the digital world. ![]() Easy to build custom forms for own group or for specific needs. Great support software for emergency operations and communications for agencies we may serve. I have asked for information to be included and got a prompt reply of how to add the information and then on the next update, it was all included. Wish more people would get on board with it. Have used it for relay through another station a couple of times and it performs well. For Peer to Peer communications, It is great. Provides flexibility to do many things and many modes of operation. Have run comparison speed tests with other popular software programs and find this to be best all round to use. The development team have done a great job of expanding and adding features including new modes to operate on. I like the add on features of Flmsg for forms and Flamp for ensuring 100% information transmittal. I have configured mainly for Windows operation but have helped others configure for Mac. I have been running this for many years and find it fantasitc to run. ![]() She participated in the 7th season of reality television series, RuPaul’s Drag Race, which aired on the Logo TV in 2015 and she ended up as a runner-up.She first began doing drag as a hobby but soon she was being booked for her performances.Pearl began her career in drag in 2012 after moving to Chicago.When she was younger, she used to draw rich old ladies with big diamond rings and furs, which later inspired her drag persona, Pearl.Pearl has stated her one of the happiest memories to be the one when she had turned 16 and moved out of her parents’ house to live independently.Source – Brightest Young Things Pearl in a selfie at Ka’au Crater in February 2018 (Pearl / Instagram) Pearl Facts Drag Queens – Dallas Dellaforce, Coco Peru, Lady Bunny.She made her first web series appearance in the series, Untucked, in 2015. ![]() Pearl made her first TV show appearance in RuPaul’s Drag Race in 2015. Billboard Dance /Electronic Albums chart and reached number 16 on the Heatseekers chart. ![]() The album contained 15 tracks and peaked at number 11 on the U.S. Pearl released her first album, Pleasure , in June 2015.
![]() On Netgear routers, you'll see the 5GHz connection as a separate Wi-Fi network in Windows. Typically, 2.4GHz is for distance, 5GHz is for performance. A lot of modern routers are dual or tri-band, offering 2.4GHz and 5GHz connections. One easy trick is to use the 5GHz connection if your router supports it. ![]() Pick a different one to the default and see if that helps. In the wireless settings this time you're looking for channel. If there are other networks nearby using the same channel, it could get congested and as such your speeds may suffer. You could try changing the channel that your Wi-Fi signal is using. If you can't move the router to a more central location, there are some things you can do. The size of the house will be one contributing factor, as will the positioning of the router. If there is no valid IP address, please perform a complete power cycle of your network, see How do I power cycle my home network?.This one is more difficult to solve, as it might not be just down to the router. For more information, see your router user manual.
Pens I’ve collected over the years-event freebies with surprisingly good ink, forgotten extras from boxed sets, novelty pieces received as gifts-have become clutter, together with the stack of old stationery and special paper that once gave me a sense of security. This shift in focus soon changed my relationship with certain belongings. The speed at which we fill up our small garbage bin with the plastic waste from our groceries constantly reminds us that our reliance on disposables needs significant improvement, and strengthens the case for growing our own food, fresh and package-free. All that water eventually seeps into the earth, and finds it way into the grass that the grazing goats feed on, and into the groundwater that our well draws from. ![]() Knowing, too, that all our wastewater ends up in the property’s drain field a quarter of a mile away inspires me to be highly conscious of the substances that go down our drains, as I can directly see the land I impact with every wash. There is a creek that supposedly runs through the ranch, but I have not seen it fill with water since we moved in August. It’s hard not to be conscious about my water consumption given the ongoing drought in Texas, which has created one of the driest years in the state in over a century. Unlike apartment living, where so much of what goes in and out is invisible, tiny home living brings everything to the forefront. In my case, I was already drawn to a life of slowness-the only mode true sustainability can thrive in-so tiny home living has been a dream of mine for years now. With the downsizing and ingenuity that come with going tiny, being more conscious about sustainability is a common byproduct of adopting this lifestyle. While the summers back home are different from the fierce, dry heat in Texas, coping with hot weather is a more familiar condition. We also rely on a small fan at the loft to circulate the cool air from below, as the warm air gathers at the top of the house where we sleep. For better thermal regulation, we plan to install blinds on our skylights before April. Cooling the house, because of its size, doesn’t require much power, but the windows and skylights let in a lot of heat, making the inverter work much harder. In the summer, conserving energy is a primary concern. A small fireplace would have been a nice feature, but, given where we live, foregoing it was a reasonable compromise. In the daytime, I never have to switch on any lights, and during the milder days of winter, we were able to get away with turning off our mini-split by relying on the sun to warm up the house in the day, and the walls’ insulation to keep it comfortable during the night. Our tiny home has two skylights that, on beautiful, sunny days, allow warmth and light to fill the space. ![]() Thankfully, weather here is more pleasant than not. We were also warned about the risk of wild animals seeking warmth and refuge under the trailer during this season, so we made sure to complete our skirting before temperatures dropped last October. If I wanted to use our washer/dryer in freezing temperatures, I would have had to winterize it, a process that requires the use of something called antifreeze (I decided to just rely on the nearby laundromat during this period). The house comes with a 25-gallon water tank that would have served as our back-up, but there seems to be a tripped circuit disabling the pump from activating that we still need to figure out. ![]() In our case, we lost water on particularly frigid days due to a malfunctioning heated hose and an insufficiently insulated water source. Winter, while generally mild in Central Texas, can be brutal on areas unprepared for the occasional subzero weather. The shaking often dissuades people from living on wheels, but we’ve greatly reduced it by using wheel chocks and supporting the trailer with hollow blocks. The house weighs over 12,000 pounds and is stabilized on eight points-it would take a tremendously powerful storm, which would batter even most ordinary homes, for the structure to be seriously damaged. Hearing the wind’s whistle accompanied by occasional shaking was unnerving at first, but anxiety about the home’s stability was soon soothed by a better understanding of its structure. During hurricane season, strong gusts and rain can rattle the house. Now, being in a country with four seasons introduced me to a myriad of other concerns that living in a tiny home on a ranch intensified. Carrying a handheld fan, umbrella, a handkerchief, a light jacket, and a fighting spirit at all times would cover most weather scenarios year-round. Having grown up in a relatively quiet neighborhood in Metro Manila, I had two primary environmental considerations: the weather- Is it raining? Are there leaks in the house, risk of flooding outside? How hot will it be today? -and the traffic. |
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